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991.
New pseudosection modelling was applied to better constrain the P–T conditions and evolution of glaucophane‐bearing rocks in the Tamayen block of the Yuli belt, recognized as the world's youngest known blueschist complex. Based on the predominant clinoamphibole, textural relationships, and mineral compositions, these glaucophane‐bearing high‐P rocks can be divided into four types. We focused on the three containing garnet. The chief phase assemblages are (in decreasing mode): amphibole + quartz + epidote + garnet + chlorite + rutile/titanite (Type‐I), phengite + amphibole + quartz + garnet + chlorite + epidote + titanite + biotite + magnetite (Type‐II), and amphibole + quartz + albite + epidote + garnet + rutile + hematite + titanite (Type‐III). Amphibole exhibits compositional zoning from core to rim as follows: glaucophane → pargasitic amphibole → actinolite (Type‐I), barroisite → Mg‐katophorite/taramite → Fe‐glaucophane (Type‐II), glaucophane → winchite (Type‐III). Using petrographic data, mineral compositions and Perple_X modelling (pseudosections and superimposed isopleths), peak P–T conditions were determined as 13 ± 1 kbar and 550 ± 40 °C for Type‐I, 10.5 ± 0.5 kbar and 560 ± 30 °C for Type‐II (thermal peak) and 11 ± 1 kbar and 530 ± 30 °C for Type‐III. The calculations yield higher pressures and temperatures than previously thought; the difference is ~1–6 kbar and 50–200 °C. The three rock types record similar P–T retrograde paths with clockwise trajectories; all rocks followed trajectories with substantial pressure decrease under near‐isothermal conditions (Type‐I and Type‐III), with the probable exception of Type‐II where decompression followed colder geotherms. The P–T paths suggest a tectonic environment in which the rocks were exhumed from maximum depths of ~45 km within a subduction channel along a relative cold geothermal gradient of ~11–14 °C km?1.  相似文献   
992.

The evolution of a solar-mass star before and on the main sequence is analyzed in light of the diminished efficiency of convection in the first 500 Myr. A numerical simulation has been performed with the CESAM2k code. It is shown that the suppression of convection in the early stages of evolution leads to a somewhat higher lithium content than that predicted by the classical solar model. In addition, the star’s effective temperature decreases. Ignoring this phenomenon may lead to errors in age and mass determinations for young stars (before the main sequence) from standard evolutionary tracks in the temperature–luminosity diagram. At a later stage of evolution, after 500 Myr, the efficiency of convection tends to the solar value. At this stage, the star’s inner structure becomes classical; it does not depend on the previous history. On the contrary, the photospheric lithium abundance contains information about the star’s past. In other words, there may exist main-sequence solar-mass stars of the same age (above 500 Myr), radius, and luminosity, yet with different photospheric lithium contents. The main results of this work add considerably to the popular method for determining the age of solar-type stars from lithium abundances.

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993.
994.
The microstructure of rock was numerically reproduced by a polygonal grain‐based model, and its mechanical behavior was examined by performing the uniaxial compression test and Brazilian tests via the Universal Distinct Element Code. The numerical results of the model demonstrated good agreement with the experimental results obtained with rock specimens in terms of the stress–strain behavior, strength characteristics, and brittle fracture phenomenon. An encouraging result is that the grain‐based model‐Universal Distinct Element Code model can reproduce a low ratio of tensile to compressive strength of 1/20 to 1/10 without the need for an additional process. This finding is ascribed to the fact that the geometrical features of polygons can effectively capture the effects of angularity, finite rotation, and interlocking of grains that exist in reality. A numerical methodology to monitor the evolution of micro‐cracks was developed, which enabled us to examine the progressive process of the failure and distinguish the contribution of tensile cracking to the process from that of shear cracking. From the observations of the micro‐cracking process in reference to the stress–strain relation, crack initiation stress, and crack damage stress, it can be concluded that the failure process of the model closely resembles the microscopic observations of rock. We also carried out a parametric study to examine the relationships between the microscopic properties and the macroscopic behavior of the model. Depending on the micro‐properties, the model exhibited a variety of responses to the external load in terms of the strength and deformation characteristics, the evolution of micro‐cracks, and the post‐peak behavior. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
995.
Much of the exposed Archean crust is composed of composite gneiss which includes a large proportion of intermediate to tonalitic material. These gneiss terranes were typically metamorphosed to amphibolite to granulite facies conditions, with evidence for substantial partial melting at higher grade. Recently published activity–composition (a?x) models for partial melting of metabasic to intermediate compositions allows calculation of the stable metamorphic minerals, melt production and melt composition in such rocks for the first time. Calculated P?T pseudosections are presented for six bulk rock compositions taken from the literature, comprising two metabasic compositions, two intermediate/dioritic compositions and two tonalitic compositions. This range of bulk compositions captures much of the diversity of rock types found in Archean banded gneiss terranes, enabling us to present an overview of metamorphism and partial melting in such terranes. If such rocks are fluid saturated at the solidus, they first begin to melt in the upper amphibolite facies. However, at such conditions, very little (< 5%) melt is produced and this melt is granitic in composition for all rocks. The production of greater proportions of melt requires temperatures ~800–850 °C and is associated with the first appearance of orthopyroxene at pressures below 8–9 kbar or with the appearance and growth of garnet at higher pressures. The temperature at which orthopyroxene appears varies little with composition providing a robust estimate of the amphibolite–granulite facies boundary. Across this boundary, melt production is coincident with the breakdown of hornblende and/or biotite. Melts produced at granulite facies range from tonalite–trondhjemite–granodiorite for the metabasic protoliths, granodiorite to granite for the intermediate protoliths and granite for the tonalitic protoliths. Under fluid‐absent conditions the melt fertility of the different protoliths is largely controlled by the relative proportions of hornblende and quartz at high grade, with the intermediate compositions being the most fertile. The least fertile rocks are the most leucocratic tonalites due to their relatively small proportions of hydrous mafic phases such as hornblende or biotite. In the metabasic rocks, melt production becomes limited by the complete consumption of quartz to higher temperatures. The use of phase equilibrium forward‐modelling provides a thermodynamic framework for understanding melt production, melt loss and intracrustal differentiation during the Archean.  相似文献   
996.
Current methods to estimate snow accumulation and ablation at the plot and watershed levels can be improved as new technologies offer alternative approaches to more accurately monitor snow dynamics and their drivers. Here we conduct a meta‐analysis of snow and vegetation data collected in British Columbia to explore the relationships between a wide range of forest structure variables – obtained from Light Detection and Ranging (LiDAR), hemispherical photography (HP) and Landsat Thematic Mapper – and several indicators of snow accumulation and ablation estimated from manual snow surveys and ultrasonic range sensors. By merging and standardizing all the ground plot information available in the study area, we demonstrate how LiDAR‐derived forest cover above 0.5 m was the variable explaining the highest percentage of absolute peak snow water equivalent (SWE) (33%), while HP‐derived leaf area index and gap fraction (45° angle of view) were the best potential predictors of snow ablation rate (explaining 57% of variance). This study reveals how continuous SWE data from ultrasonic sensors are fundamental to obtain statistically significant relationships between snow indicators and structural metrics by increasing mean r2 by 20% when compared to manual surveys. The relationships between vegetation and spectral indices from Landsat and snow indicators, not explored before, were almost as high as those shown by LiDAR or HP and thus point towards a new line of research with important practical implications. While the use of different data sources from two snow seasons prevented us from developing models with predictive capacity, a large sample size helped to identify outliers that weakened the relationships and suggest improvements for future research. A concise overview of the limitations of this and previous studies is provided along with propositions to consistently improve experimental designs to take advantage of remote sensing technologies, and better represent spatial and temporal variations of snow. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
997.
For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m3/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m3/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
998.
Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.  相似文献   
999.
New activity–composition (ax) relations for minerals commonly occurring in metapelites are presented for use with the internally consistent thermodynamic dataset of Holland & Powell ( 2011 , Journal of Metamorphic Geology, 29 , 333–383). The ax relations include a broader consideration of Fe2O3 in minerals, changes to the formalism of several phases and order–disorder in all ferromagnesian minerals where Fe–Mg mixing occurs on multiple sites. The ax relations for chlorite, biotite, garnet, chloritoid, staurolite, cordierite, orthopyroxene, muscovite, paragonite and margarite have been substantially reparameterized using the approach outlined in the companion paper in this issue. For the first time, the entire set of ax relations for the common ferromagnesian minerals in metapelitic rocks is parameterized simultaneously, with attention paid to ensuring that they can be used together to calculate phase diagrams of geologically appropriate topology. The ax relations developed are for use in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) system for both subsolidus and suprasolidus conditions. Petrogenetic grids in KFMASH and KFMASHTO are similar in topology to those produced with earlier end‐member datasets and ax relations, but with some notable differences. In particular, in subsolidus equilibria, the FeO/(FeO + MgO) of garnet is now greater than in coexisting staurolite, bringing a number of key staurolite‐bearing equilibria into better agreement with inferences from field and petrographic observations. Furthermore, the addition of Fe3+ and Ti to a number of silicate phases allows more plausible equilibria to be calculated in relevant systems. Pseudosections calculated with the new ax relations are also topologically similar to equivalent diagrams using earlier ax relations, although with many low variance fields shifting in PT space to somewhat lower pressure conditions.  相似文献   
1000.
Oxygen isotopes are an attractive target for zoning studies because of the ubiquity of oxygen‐bearing minerals and the dependence of mineral 18O/16O ratios on temperature and fluid composition. In this study, subtle intragrain oxygen isotope zoning in titanite is resolved at the 10‐μm scale by secondary ion mass spectrometry. The patterns of δ18O zoning differ depending on microstructural context of individual grains and reflect multiple processes, including diffusive oxygen exchange, partial recrystallization, grain‐size reduction, and grain growth. Using the chronological framework provided by structural relations, these processes can be related to specific events during the Grenville orogeny. Titanite was sampled from two outcrops within the Carthage‐Colton Mylonite Zone (CCMZ), a long‐lived shear zone that ultimately accommodated exhumation of the Adirondack Highlands from beneath the Adirondack Lowlands during the Ottawan phase (1090–1020 Ma) of the Grenville orogeny. Titanite is hosted in the Diana metasyenite complex, which preserves three sequentially developed fabrics: an early NW‐dipping protomylonitic fabric (S1) is crosscut by near‐vertical ultramylonitic shear zones (S2), which are locally reoriented by a NNW‐dipping mylonitic fabric (S3). Texturally early titanite (pre‐S2) shows diffusion‐dominated δ18O zoning that records cooling from peak Ottawan, granulite‐facies conditions. Numerical diffusion models in the program Fast Grain Boundary yield good fits to observed δ18O profiles for cooling rates of 50 ± 20 °C Ma?1, which are considerably faster than the 1–5 °C Ma?1 cooling rates previously inferred for the Adirondack Highlands from regional thermochronology. High cooling rates are consistent with an episode of rapid shearing and exhumation along the CCMZ during gravitational collapse of the Ottawan orogen at c. 1050 Ma. Texturally later titanite (syn‐S2) has higher overall δ18O and shows a transition from diffusion‐dominated to recrystallization‐dominated δ18O zoning, indicating infiltration of elevated‐δ18O fluids along S2 shear zones and continued shearing below the blocking temperature for oxygen (~≤500 °C for grain sizes at the study site). The texturally latest titanite (post‐S3) has growth‐dominated δ18O zoning, consistent with porphyroblastic grain growth following cessation of shearing along the Harrisville segment of the CCMZ.  相似文献   
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